Schulte, Robin
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Schulte, Robin
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Publication Access status: Metadata only , Bis‐ and Tris‐norbornadienes with High Energy Densities for Efficient Molecular Solar Thermal Energy StorageMolecular solar thermal energy storage (MOST) systems can convert, store and release solar energy in chemical bonds, i.e., as chemical energy. In this work, phenyl‐ and naphthyl‐linked bis‐ and tris‐norbornadienes are presented as promising MOST systems with very high energy densities. The substrates were synthesized by Suzuki–Miyaura coupling reactions and their absorption properties and characteristic parameters for MOST applications were investigated. The norbornadiene derivatives showed absorption onsets of up to 386 nm and photoisomerization quantum yields of 56 % per photoisomerization event. The resulting quadricyclane products have half‐lifes up to 14 d and very high energy densities of up to 734 kJ/kg. Overall, these norbornadienes fulfill necessary criteria for an optimal MOST system and are, therefore, a highly promising basis for the development of materials for efficient solar energy conversion and storage.Source Type:Article3 - Some of the metrics are blocked by yourconsent settings
Publication Access status: Metadata only , Gilding the Lily: Studies on the Effects of Successive Loading of Light Energy‐Storing Molecules with Norbornadiene UnitsThe photochromic norbornadiene‐quadricyclane cycle has emerged as a promising basis for molecular solar thermal (MOST) energy storage. In this context, it has been established that multifunctional photoswitches with several norbornadiene units at one central aromatic core have favorable photochemical properties and storage capacities. Nevertheless, a maximum number of three norbornadiene units has been combined in one molecule, so far. In this work, scope and limits of this approach should be further assessed. Thus, exemplary polyfunctionalized derivatives have been synthesized by Suzuki‐Miyaura reactions, and their suitability for MOST applications was investigated. These compounds were converted into the corresponding quadricyclanes by direct UV irradiation ( λ ex =315 nm) with moderate quantum yields, whereas the reaction is more efficient upon irradiation with λ ex =520 nm in the presence of photosensitizers. But these molecules showed low stabilities and short half‐lives of 1 to 2 days. Moreover, the photochemical reaction is hampered by the close vicinity of photoactive units. Therefore, it appears that in such assemblies, a maximum number of three norbornadiene units is the limit to keep the optimal balance of photochemical properties required for MOST applications.Source Type:Article3 - Some of the metrics are blocked by yourconsent settings
Publication Access status: Metadata only , Monoaryl‐Substituted Norbornadiene Photoswitches as Molecular Solar Thermal Energy Storage Compounds: Synthesis and InvestigationIn the search for improved photochromic systems that may be used for the efficient reversible conversion of light into chemical energy, eight monoaryl‐substituted norbornadienes are presented, which carry naphthyl, anthracenyl, or donor‐acceptor‐phenyl substituents to establish an extended π system. The substrates were synthesized by Suzuki‐Miyaura coupling reactions, and their absorption properties, the key parameters of the photochromic equilibrium, and the energy storage density of the quadricyclane products were examined. It was observed that these compounds have favorable properties for chemical energy storage. Specifically, 2‐(1‐naphthyl)norbornadiene showed a pronounced red shift of the absorption, a long half‐life (35 d) and a relatively high energy storage density (361 KJ/Kg) of the respective quadricyclane. Therefore, the so far neglected monoaryl‐norbornadienes represent a useful and complementary class of compounds that should be considered in the development of efficient molecular solar thermal energy storage (MOST) compounds, which can reversibly convert sunlight into chemical energy.Source Type:Article2
