Mondal, Debabrata
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Publication Access status: Metadata only , Concurrent tandem catalysis enabled by nanomechanical motion in heteroleptic four-component dual-catalyst machineryThe stochastic motion (45 kHz) of a biped in a dynamic slider-on-deck kicks out a basic organocatalyst into solution while parallel freeing a silver( i ) site with both synergistically running a tandem Michael addition/hydroalkoxylation cyclization.Source Type:Article3 - Some of the metrics are blocked by yourconsent settings
Publication Access status: Metadata only , Dissipative sequential catalysis via six-component machineryTriphenyl phosphane (TPP) and an epoxide as a fuel system transiently transformed a non-catalytic six-component turnstile into a four-component catalytic rotor releasing N -methyl pyrrolidine and a copper( i ) complex.Source Type:Article1 - Some of the metrics are blocked by yourconsent settings
Publication Access status: Metadata only , Stepwise Dissipative Control of Multimodal Motion in a Silver(I) CatenateStepwise dissipative control of two distinct motions, i.e., shuttling and sliding, is demonstrated in a single multicomponent device. When [2]rotaxane 1 , which acts as a biped, and deck 2 were treated with AgBF 4 /PhCH 2 Br+NEt 3 as chemical fuel, the transient catenate [Ag( 1 )] + ⋅ [Ag 3 ( 2 )] 3+ was instantly generated showing multimodal motion and autonomous return to 1 and 2 . In the dissipative process, catenate [Ag( 1 )] + ⋅ [Ag 3 ( 2 )] 3+ cleanly transformed into the follow‐up transient device ( 1 ) ⋅ [Ag 3 ( 2 )] 3+ exhibiting only sliding motion. Two interference‐free dissipative cycles proved the resilience and robustness of the process.Source Type:Article
