Now showing 1 - 5 of 5
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    Publication
    A Constitutionally Dynamic Cage Acts as a Convertible and Adaptable Information Manager in Supramolecular Logic
    (2023)
    Rajasekaran, Vishnu Verman 
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    Mondal, Debabrata 
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    Schmittel, Michael 
    A three‐component molecular ensemble consisting of the constitutionally dynamic cage 1 , rotaxane 2 and luminophore 3 acts as a signal transducer which assimilates three input signals, i. e., Zn 2+ , H + , and Cu + , to perform individual logic operations (e. g. a 3‐input NOR gate with catalytic output, 3‐input AND gate with optical output) and operates as an unconventional 3‐input demultiplexer.
    Source Type:
      1
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    Publication
    Concurrent tandem catalysis enabled by nanomechanical motion in heteroleptic four-component dual-catalyst machinery
    (2023) ; ;
    Mondal, Debabrata 
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    Schmittel, Michael 
    The stochastic motion (45 kHz) of a biped in a dynamic slider-on-deck kicks out a basic organocatalyst into solution while parallel freeing a silver( i ) site with both synergistically running a tandem Michael addition/hydroalkoxylation cyclization.
    Source Type:
      3
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    Publication
    Dissipative sequential catalysis via six-component machinery
    (2024)
    Mondal, Debabrata 
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    ; ;
    Schmittel, Michael 
    Triphenyl phosphane (TPP) and an epoxide as a fuel system transiently transformed a non-catalytic six-component turnstile into a four-component catalytic rotor releasing N -methyl pyrrolidine and a copper( i ) complex.
    Source Type:
      1
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    Publication
    Proton transfer network with luminescence display controls OFF/ON catalysis that generates a high-speed slider-on-deck
    (2023) ; ;
    Mondal, Debabrata 
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    Rajasekaran, Vishnu Verman 
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    Goswami, Abir 
    Upon addition/removal of silver( i ) ions and due to efficient inter-component communication, a supramolecular multicomponent network acts as an OFF/ON proton relay with luminescence display enabling switchable catalysis.
    Source Type:
      2
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    Publication
    Stepwise Dissipative Control of Multimodal Motion in a Silver(I) Catenate
    (2024) ; ;
    Mondal, Debabrata 
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    Paululat, Thomas 
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    Schmittel, Michael 
    Stepwise dissipative control of two distinct motions, i.e., shuttling and sliding, is demonstrated in a single multicomponent device. When [2]rotaxane 1 , which acts as a biped, and deck 2 were treated with AgBF 4 /PhCH 2 Br+NEt 3 as chemical fuel, the transient catenate [Ag( 1 )] + ⋅ [Ag 3 ( 2 )] 3+ was instantly generated showing multimodal motion and autonomous return to 1 and 2 . In the dissipative process, catenate [Ag( 1 )] + ⋅ [Ag 3 ( 2 )] 3+ cleanly transformed into the follow‐up transient device ( 1 ) ⋅ [Ag 3 ( 2 )] 3+ exhibiting only sliding motion. Two interference‐free dissipative cycles proved the resilience and robustness of the process.
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