Citation Link: https://doi.org/10.3390/cryst13030511
Luminescence Properties of Y3F[Si3O10]:Ln3+ (Ln = Eu, Tb, Er) with Thalenite-Type Host Lattice and Crystal Structure of Tm3F[Si3O10]
Publication Type
Article
Subjects
Monoclinic crystal system
Luminescence
Crystal structure
Chemistry
Crystallography
Molar ratio
Ion
Emission spectrum
Analytical Chemistry (journal)
Spectral line
Materials science
Physics
Catalysis
Date Issued
2023
Abstract
With Tm3F[Si3O10], a new representative of the Ln3F[Si3O10] series could be synthesized by the reaction of Tm2O3, TmF3 and SiO2 (molar ratio: 1:1:3), applying an excess of CsBr as a fluxing agent in gas-tightly sealed platinum crucibles for eight days at 750 °C, and designed to yield Tm3F3[Si3O9] or Cs2TmF[Si4O10]. Single crystals of Tm3F[Si3O10] (monoclinic, P21/n; a = 725.04(6), b = 1102.43(9), c = 1032.57(8) pm, β = 97.185(7)°; Z = 4) appear as pale celadon, transparent, air- and water-resistant rhombic plates. According to its thalenite-type structure, Tm3F[Si3O10] contains catena-trisilicate anions [Si3O10]8− and triangular [FTm3]8+ cations. The three crystallographically different Tm3+ cations are coordinated by seven plus one (Tm1) or only seven anions (Tm2 and Tm3) exhibiting a single F− anion for each polyhedron, additional to the majority of O2− anions. Furthermore, the luminescence properties of the isotypic colorless compound Y3F[Si3O10] doped with Eu3+ (red emission), Tb3+ (green emission) and Er3+ (yellow and infrared emission), respectively, are reported in presenting their different excitation and emission spectra.
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